In the first half, Di Maria received a welcome back from former teammate Ashley Young when the United captain barged him into the advertising hoards as the ball went out for a throw in, to huge applause from the crowd.
As the PSG players celebrated on the byline, an incensed Di Maria let out his frustration by screaming "F*ck off!"
Di Maria was the architect for PSG's victory, which will only further rile those who remember his failed United stint well.
The winger picked out Presnel Kimpembe from a corner for PSG's opener in the 53rd minute, before setting up Kylian Mbappe with a cross to score the second seven minutes later. He showed no lack of desire in getting to the ball but it was noticeable that he was often being shadowed by Marquinhos whenever United were in possession, a clear sign of PSG head coach Thomas Tuchel attempting to shackle the World Cup victor. 'He (Young) plays many, many times here, and he knows there is a hill, so there was no need to push Di Maria into the fans. Di Maria was handed the famed No. 7 jersey at the club, but the pacey wide man never really managed to live up to the lofty expectations that were placed on him upon his arrival.
Eventually, it was made clear that Pogba had been shown a second yellow card for his poorly timed challenge on Dani Alves, having already been booked in the first half.
But late in the first half, Di Maria's end was up.
'I think he was lucky because it was not necessary, ' said Tuchel.
There wasn't much doubt which way it was going to go for Angel di Maria. "If you tease him, it does not make him weaker", he said, Sky Sports reported. 90 more minutes are missing To continue working for what is coming.